Active bilayer films of thermoplastic starch and polycaprolactone obtained by compression molding

Crosslinking of oxidized thermoplastic starch films

Tailoring barrier properties of thermoplastic corn starch-based films (TPCS) by means of a multilayer design.

This work compares the effect of adding different biopolyester electrospun coatings made of polycaprolactone (PCL), polylactic acid (PLA) and polyhydroxybutyrate (PHB) on oxygen and water vapour barrier properties of a thermoplastic corn starch (TPCS) film. The morphology of the developed multilayer structures was also examined by Scanning Electron Microscopy (SEM). Results showed a positive li...

Physical and/or Chemical Modifications of Starch by Thermoplastic Extrusion

Starch makes up the nutritive reserves of many plants. Starch biosynthesis is a complex process, which may be summarized as during the growing season, the green leaves collect energy from the sun, this energy is transported as a sugar solution to the starch storage cells, and the sugar is converted into starch in the form of tiny granules occupying most of the cell interior. The conversion of s...

Retrogradation and Antiplasticization of Thermoplastic Starch

Petrochemical-based plastics are widely used in modern society due to their high effective mechanical and barrier properties (Farris et al., 2009; Siracusa et al., 2008). However, petrochemical-based plastics have become an environmental concern as they are not biodegradable or recyclable. Replacing the petrochemical-based polymers with biopolymers which are renewable has become an attractive i...

Thermoplastic Polymer Shrinkage in Emerging Molding Processes

In this paper, in situ experiments have been designed using the full-field deformation technique of Digital Image Correlation (DIC) to characterize non-uniform shrinkage in thermoplastic polymers commonly used in traditional and emerging molding processes. These experiments are capable of characterizing the differences in strains that develop due to thermal gradients and stiction as the polymer...